catena-Poly[[[aqua(2,2′-bipyridine-κ2 N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2 O 2:O 5] dihydrate]
نویسندگان
چکیده
In the crystal structure of the title compound, {[Cu(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite chain parallel to [110] is formed by the linking of Cu(H(2)O)(2,2'-bipyridine) units through a furan-2,5-dicarboxyl-ate bridge. The Cu(II) atom shows a square-pyramidal geometry, with one furan-2,5-dicarboxyl-ate O atom in the apical position. The dihedral angle between the planes of the furan ring and the bipyridine mol-ecule is 83.88 (7)°. O(water)-H⋯O hydrogen bonds connect adjacent chains, generating a layer motif parallel to (001).
منابع مشابه
catena-Poly[[[aqua(2,2′-bipyridine-κ2 N,N′)zinc]-μ-furan-2,5-dicarboxylato-κ2 O 2:O 5] dihydrate]
In the title hydrated coordination polymer, {[Zn(C6H2O5)(C10H8N2)(H2O)]·2H2O} n , an infinite [1-10] chain is formed by the linking of [Zn(C10H8N2)(H2O)](2+) entities by bridging, monodentate furan-2,5-dicarboxyl-ate dianionic linkers. The Zn(2+) coordination geometry is a trigonal bipyramid, with one N atom (from 2,2'-bipyridine) and one O atom (from the bridging dianion) in the axial position...
متن کاملBis(μ-3-nitrophthalato-κ2 O 1:O 2)bis[aqua(2,2′-bipyridine-κ2 N,N′)copper(II)] dihydrate
Two 3-nitro-phthalate dianions bridge two water-coordinated 2,2'-bipyridine-chelated Cu(II) atoms about a center of inversion to generate the title dinuclear compound, [Cu(2)(C(8)H(3)NO(6))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O. The geometry of the Cu(II) atom is a distorted square pyramid. Adjacent mol-ecules are linked through the coordinated and solvent water mol-ecules to form a linear rib...
متن کاملcatena-Poly[[aqua(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ2 O:O′]
In the title compound, [Cu(C(14)H(8)O(5))(C(12)H(12)N(2))(H(2)O)](n), the Cu(II) ion is penta-coordinated in a square-pyramidal geometry. Two N atoms of the chelating 5,5'-dimethyl-2,2'-bipyridine (dbp) ligand and two O atoms of two different 2,2'-oxydibenzoic (odb) ligands occupy the basal plane while the water O atom completes the square-pyramidal geometry at the apical site. The non-water N(...
متن کاملcatena-Poly[[[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ2 O 2:O 3] [[(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ2 O 2:O 3]]
In the title compound, {[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))(H(2)O)]·[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))]}(n), one Zn(2+) ion is five-coordin-ated by two O atoms from two different 3-chloro-benzene-1,2-dicarboxyl-ate ligands, one O atom from a water mol-ecule and two N atoms from a 4,4'-dimethyl-2,2'-bipyridine ligand, while the second Zn(2+) ion is four-coordinated by two O atoms from two diffe...
متن کاملBis(μ-pyridine-2,5-dicarboxylato)-κ3 N,O 2:O 5;κ3 O 5:N,O 2-bis[aqua(2,2′-bipyridine-κ2 N,N′)cobalt(II)] dihydrate
In the centrosymmetric title compound, [Co(2)(C(7)H(3)NO(4))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, the two Co(II) cations are bridged by pairs of pyridine-2,5-dicarboxyl-ate anions across an inversion center. Besides two pyridine-2,5-dicarboxyl-ate anions, one bidentate 2,2'-bipyridine and one water mol-ecule coordinate to the Co cation, completing a distorted octa-hedral coordination geometr...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012